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Molecular chirality: A new approach from a dynamical point of view
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نویسنده
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hirota e.
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منبع
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proceedings of the japan academy series b-physical and biological sciences - 2017 - دوره : 93 - شماره : 10 - صفحه:841 -849
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چکیده
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The double minimum potential (dmp),which hund assumed to explain the quantum-mechanical stability of enantiomers,was discussed,by citing three typical examples of dmp: inversion,internal rotation,and puckering. they expanded the classical scope of chirality,as defined by kelvin,and indicated that a new bridge could be formed between the three low-frequency dmp modes and the asymmetric syntheses of chiral molecules. © 2017 the japan academy.
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کلیدواژه
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Asymmetric syntheses; Chiral molecule; Double minimum potential; Low-frequency mode
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آدرس
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the graduate university for advanced studies,hayama,kanagawa, Japan
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Authors
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