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Studies on the base-induced rearrangement of 5-methyl-3-nitrosoindolizine derivatives
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نویسنده
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wang p. ,cai j. ,chen j. ,ji m.
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منبع
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journal of the chemical society of pakistan - 2015 - دوره : 37 - شماره : 6 - صفحه:1185 -1191
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چکیده
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Here we have studied the rearrangement of 5-methyl-3-nitrosoindolizine derivatives in the presence of k2co3. 5-methyl-3-nitrosoindolizine derivatives can be converted to ring-opening,rearrangement and denitrosylation products respectively. methyl at 5-position and substituent groups at 2-position of 3-nitrosoindolizine derivatives are critical for the rearrangement reaction and have slight effect on the denitrosylation under standard conditions.
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کلیدواژه
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Denitrosylation; Indolizine; Rearrangement; Ring-opening
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آدرس
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department of biomedical engineering,school of engineering,china pharmaceutical university,nanjing,china,school of biological science and medical engineering,southeast university, China, school of chemistry and chemical engineering,southeast university, China, school of chemistry and chemical engineering,southeast university, China, school of biological science and medical engineering,southeast university, China
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Authors
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