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Mixed ligand copper(II) complexes of pyrrolidinedithiocarbamate and diamines
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نویسنده
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ahmad s. ,sarwar m. ,ahmad s. ,ali s. ,khurram department of chemistry
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منبع
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journal of the chemical society of pakistan - 2010 - دوره : 32 - شماره : 4 - صفحه:443 -448
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چکیده
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Copper(ii) complexes of pyrrolidinedithiocarbamate (pdtc) and diamines having the general formula,[cu(diamine)(pdtc)]cl,[cu(diamine)cl 2][cu(pdtc)cl] or [cu2(diamine)(pdtc)2cl 2] (diamine = 1,3-diaminopropane,n,n′-dimethylethylenediamine,n,n,n′,n′tetramethylethylenediamine and 1,2-phenylenediamine) have been prepared and characterized by ir spectroscopy and thermal analysis. the results of thermal analysis are consistent with the proposed composition of the complexes. the ir data suggest that coordination of the pyrrolidinedithiocarbamate (pdtc) takes place through the two sulfur atoms in a symmetrical bidentate fashion.
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آدرس
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department of chemistry,university of engineering and technology, Pakistan, department of chemistry,university of engineering and technology, Pakistan, department of chemistry, Pakistan, department of chemistry, Pakistan, university of engineering and technology, Pakistan
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Authors
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