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Regiospecific Mno 2 catalyzed hydration of phenylmethylene malononitriles to cyanophenylacrylamides by oximes
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نویسنده
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rauf a. ,awan f.s. ,mumtaz s. ,sharif a. ,ahmed e. ,arshad m. ,kausar f. ,yasmin g. ,qureshi a.m.
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منبع
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journal of the chemical society of pakistan - 2012 - دوره : 34 - شماره : 3 - صفحه:728 -731
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چکیده
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A novel and convenient method for the regiospecific hydration of phenylmethylene malononitriles to cyanoacrylamides was developed; scope of the method and reaction conditions were optimized extensively,the method was found to be extremely successful in hydration of anti nitrile to phenyl group only in phenylmethylene malononitriles. this regiospecificity is owed mainly to steric factors.
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آدرس
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department of chemistry,islamia university, Pakistan, department of chemistry,bahauddin zakariya university, Pakistan, department of chemistry,bahauddin zakariya university, Pakistan, institue of chemistry,university of the punjab, Pakistan, institue of chemistry,university of the punjab, Pakistan, department of chemistry,comsats institute of information technology, Pakistan, department of chemistry,bahauddin zakariya university, Pakistan, department of chemistry,bahauddin zakariya university, Pakistan, department of chemistry,bahauddin zakariya university, Pakistan
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Authors
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