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Characterization and crystal structure of trans-dichloro(Bis- Thiocarbohydrazide) cadmium(II)
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نویسنده
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hakimi m. ,feizi n. ,abbasi f. ,takjoo r. ,schuh e. ,mohr f.
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منبع
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journal of the chemical society of pakistan - 2012 - دوره : 34 - شماره : 3 - صفحه:679 -682
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چکیده
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The preparation and spectroscopic characterization of trans- dichloro(bisthiocarbohydrazide) cadmium(ii) using uv-vis,raman and ir spectroscopies is reported is reported in this paper. molecular structure of the complex was determined by single-crystal x-ray diffraction. the compound crystallizes in the monoclinic crystal system,space group p2 1/n,z = 4,v = 594.91(5) å3 with unit cell parameters a = 8.6136(4) å,b = 5.7881(3) å,c = 12.0980(6) å and b= 99.487(5) °. the cadmium (ii) ion is bound to sulfur and nitrogen atoms of two thiocarbohydrazide ligands as well as two chloride ions in an octahedral geometry about cd.
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کلیدواژه
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Cadmium (II); Crystal structure; Hydrogen bonding; Thiocarbohydrazide
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آدرس
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payame noor university, ایران, payame noor university, ایران, payame noor university, ایران, department of chemistry,school of sciences, ایران, fachbereich c - anorganische chemie, Germany, fachbereich c - anorganische chemie, Germany
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Authors
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