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Synthesis and X-ray crystallographic study of N-(2-((2,6- diisopropylphenylimino)methyl)phenyl)benzene-1,2-diamine
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نویسنده
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zhang z.q. ,zhang y. ,chen b.r. ,jiang h.j. ,yao y.m.
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منبع
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journal of the chemical society of pakistan - 2012 - دوره : 34 - شماره : 4 - صفحه:1048 -1051
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چکیده
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The title compound n-(2-((2,6-diisopropylphenylimino)methyl)phenyl) benzene-1,2-diamine(c 25h 29n 3,mr = 371.51) was synthesized by the metathesis reactions in high yield. the compound was studied in the solution state by 1h-nmr spectroscopy and the solid state structure was determined by x-ray structural analysis. the title complex crystallizes in the p¶ space group(triclinic) with the crystal cell parameters a = 10.763 (3) å,b = 10.784 (3) å,c = 11.433 (3) å α = 107.330 (2)°,β = 107.658 (2)°,γ = 110.335 (3)°,v = 1058.1 (4) å 3 and z = 2. x-ray analysis reveals that the atoms of c(1) to c(8),n(1) and n(2) form a planar and n2,c3,c2,c1 and n1 atoms can form a conjugated system. the structure in solution is in agreement with the solid-state structure.
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آدرس
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school of pharmacy, China, department of chemistry and chemical engineering,key laboratory of organic synthesis of jiangsu, China, school of pharmacy, China, school of pharmacy, China, department of chemistry and chemical engineering,key laboratory of organic synthesis of jiangsu, China
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Authors
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