SEM-EDX and FTIR studies of chlorinated rubber coating

Anticorrosive performance of chlorinated rubber coating has been investigated by visual examination,scanning electron microscopy (sem)/energy dispersive x-ray (edx) analysis and fourier transform infrared (ftir) spectroscopy. after surface preparation,commercially available coating system based on chlorinated rubber (primer)/chlorinated rubber (topcoat) formulation was applied on mild steel test panels (10cm x 15cm sizes). prepared coated panels were exposed at marine,industrial and urban test sites located in karachi,pakistan according to iso 8565 norm. accelerated testing was performed by using a salt spray chamber (astm b117 norm). accelerated weathering methods are the methods in which the factors responsible for the degradation of coatings are artificially intensified in order to achieve the rapid degradation of coatings. visual examination of blistering and rusting as well as sem micrographs indicated a more severe degradation of the coating surface characteristics at natural exposure testing sites (particularly at marine test site) than for accelerated (salt spray) testing. edx determination of the oxygen/carbon (o/c) ratios also indicated increased degradation at natural test sites compared to the accelerated (salt spray) testing. photooxidation of the binder results in the formation of carbonyl compounds as revealed by ftir spectroscopy which also indicated dehydrochlorination.