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Kinetics and Electrochemical Studies of Uranium in Perchlorate and Sulphate Media by Cyclic Voltammetry
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نویسنده
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ALI KHAN ABDUL SATTAR ,AHMED RIAZ ,MIRZA MUHAMMAD LATIF
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منبع
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journal of the chemical society of pakistan - 2008 - دوره : 30 - شماره : 2 - صفحه:170 -177
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چکیده
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The cyclic voltammetric behavior of uranyl ion was investigated at hanging mercury drop electrode in perchlorate supporting electrolyte. the standard heterogeneous electrons transfer rate constant k, for the reduction of uranium from u(vi) to u(v) state was 2.72×10^-1 cm sec^-1 in simple perchlorate medium and in the presence of 0.40 mol l^-1 sulphate ions the value of k. was 2.56 × 10^-1 cm sec^-1.
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آدرس
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Pakistan Institute of Nuclear Science and Technology, Chemistry Division, Pakistan, Pakistan Institute of Nuclear Science and Technology, Chemistry Division, Pakistan, Islamia University of Bahawalpur, Department of Chemistry, Pakistan
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Authors
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