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synthesis and investigation of corrosion inhibition of 4-(naphthalen-1-yl) thiazol-2-amineoncopper in hcl: experimental and theoretical studies
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نویسنده
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mousavi-khoshdel s. morteza ,rezania hamidreza (jafar) ,ghaffarinejad ali ,farahati razieh
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منبع
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journal of applied chemical research - 2021 - دوره : 15 - شماره : 3 - صفحه:88 -105
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چکیده
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4-(naphthalen-1-yl) thiazol-2-amine (nta) was synthesized and its corrosion inhibition ability on the copper was investigated. the inhibition efficiencies were evaluated by electrochemical impedance spectroscopy (eis), potentiodynamic polarization, scanning electron microscopy (sem), and atomic force microscopy (afm).the experiments were performed in various concentrations of nta in 1 m hcl solution. computational studies (molecular dynamics (md) simulation and density functional theory (dft)) were also executed. the corrosion inhibition efficiency of this compound at optimum concentration was about 90%, demonstrating that nta is an effective corrosion inhibitor. the adsorption of inhibitor obeyed the langmuir adsorption model.
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کلیدواژه
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copper ,eis ,md ,corrosion inhibition ,thiazole
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آدرس
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iran university of science and technology, faculty of chemistry, industrial electrochemistry research laboratory, iran, kharazmi university, faculty of chemistry, department of organic chemistry, iran, iran university of science and technology, faculty of chemistry, electroanalytical chemistry research center, industrial electrochemistry research laboratory,research laboratory of real samples analysis, iran, iran university of science and technology, faculty of chemistry, industrial electrochemistry research laboratory, iran
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پست الکترونیکی
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r_farahati@yahoo.com
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Authors
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