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Bis(Alkyne) Copper(I) Trifluoracetate: Synthesis, Characterization, and Solid-State Structure
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نویسنده
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Al-Anber Mohammed A. ,Walfort Bernhard ,Lang Heinrich
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منبع
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jordan journal of chemistry - 2010 - دوره : 5 - شماره : 3 - صفحه:231 -238
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چکیده
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Heterobimetallic {[ti](μ-σ,π-c≡csime3)2}cuo2ccf3 (3) ([ti] = (η5-c5h4sime3)2ti) was synthesized by reacting the organometallic π-tweezer molecule [ti](c≡csime3)2 (1) with stoichiometric amounts of 1/n[cuo2ccf3]n (2). the structure of 3 in the solid state was determined by single x-ray structure analysis indicating that a mononuclear copper(i) carboxylate unit with a tri-coordinated copper atom is present. within this building block the titanium alkynyl ligands are chelate-bonded to the group-11 metal atom.
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کلیدواژه
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Heterobimetallic; Organometallic π-Tweezer; Titanium; Copper(I) Trifluoroacetate; X-ray Structure
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آدرس
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Mu´tah University, Faculty of Science, Department of Chemical Science, Jordan, Technische Universitat Chemnitz, Institut fur Chernie, Lehrstuhl fur Anorganische Chemie, Germany, Technische Universitat Chemnitz, Fakultät für Naturwissenschaften, Institut fur Chernie, Lehrstuhl fur Anorganische Chemie, Germany
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پست الکترونیکی
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heinrich.lang@chemie.tu-chemnitz.de
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Authors
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