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Indium-Mediated Allylation of N-tert-Butylsulfinylaldimines with Dimethyl 2-[2-(Chloromethyl)allyl]malonate
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نویسنده
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Dema Haythem K. ,Foubelo Francisco ,Yus Miguel
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منبع
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jordan journal of chemistry - 2011 - دوره : 6 - شماره : 3 - صفحه:247 -255
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چکیده
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The reaction of n-tert-butylsulfinylaldimines 5 with dimethyl 2-[2-(chloromethyl)allyl]-malonate (10), in the presence of indium metal and sodium iodide, at room temperature for 72hours, led to the corresponding amino ester derivative 11. the reaction preceeded in high yields and in a total stereoselective fashion, a single diastereoisomer being always isolated.
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کلیدواژه
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N-tert-Butylsulfinylaldimines; Diastereoselective allylation; Indium; Amino esters.
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آدرس
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University of Alicante, Faculty of Science, Institute of Organic Synthesis (ISO), Department of Organic Chemistry, Spain, University of Alicante, Faculty of Science, Institute of Organic Synthesis (ISO), Department of Organic Chemistry, Spain, University of Alicante, Faculty of Science, Institute of Organic Synthesis (ISO), Department of Organic Chemistry, Spain
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Authors
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