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Hydrolysis of Thallium Phthalimide. the Crystal Structure of Dimorph Polymeric Thallium(I) Complex, {Tl[(Hphthalate)]}n
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نویسنده
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Abu-Salem Qutaiba ,Mallah Eyad ,Said Farouq F. ,Ali Basem F. ,Steinmann Manfred ,Voelter Wolfgang
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منبع
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jordan journal of chemistry - 2012 - دوره : 7 - شماره : 2 - صفحه:163 -172
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چکیده
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Single crystals of [tl(hphthalate)]n, were grown by hydrolysis of thallium phthalimide during slow evaporation of an aqueous solution at room temperature, and the structure was determined by x-ray diffraction analysis. it has been characterized also by elemental analysis,nmr, and ir spectroscopy. the crystals belong to the monoclinic crystal system space groupp21/c. its crystal structure analysis reveals that there is (tlo6) six coordinate tl atoms. inaddition, the coordination geometry of tl^+ may be influenced by its stereochemically active lone pair. the complex is linked via intermolecular o-h···o hydrogen bonding.
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کلیدواژه
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Hydrogen Bond; Crystal Structure; Thallium ,Phthalate Ligand.
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آدرس
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Al al-Bayt University, Faculty of Science, Department of Chemistry, Jordan, Petra University, Faculty of Pharmacy and Medical Sciences, Jordan, Al al-Bayt University, Faculty of Science, Department of Chemistry, Jordan, Al al-Bayt University, Faculty of Science, Department of Chemistry, Jordan, University of Tübingen, Institute for Inorganic Chemistry, Germany, University of Tübingen, Interfacultary Institute of Biochemistry, Germany
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Authors
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