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Synthesis and Crystal Structure of Thiocyanate Bridged One Dimensional Polymeric Complex of Cadmium(II)
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نویسنده
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ZHOU Yong-hong ,TIAN Yu-peng
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منبع
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jordan journal of chemistry - 2012 - دوره : 7 - شماره : 1 - صفحه:1 -7
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چکیده
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A new one-dimensional polymeric complex [cd(dmab)2(scn)2]n (dmab = 4- dimethylaminobenzaldehyde) (1) has been synthesized and characterized by elementalanalyses, ir and single crystal x-ray crystallography. it crystallizes in the monoclinic spacegroup of p21/c with a = 5.8673(5) å, b = 7.4615(8) å, c = 25.411(2) å, β = 91.9320(10)°, and z = 2. crystal structure shows that the one-dimensional chain is propagated through doubly bridging thiocyanate and dmab acts as terminal ligand. furthermore, thermal stability and luminescent property of 1 were investigated.
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کلیدواژه
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Cadmium(II); Crystal structure; 4-Dimethylaminobenzaldehyde; Thiocyanate bridging.
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آدرس
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Huaibei Normal University, School of Chemistry and Material Science, China, Anhui University, Department of Chemistry and Chemical Technology, China
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Authors
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