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3,3,4,4-Tetraethoxybutyne – An Excellent Starting Material for the Synthesis of Range of Functionalized Compounds
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نویسنده
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Sydnes Leiv K. ,Holmelid Bjarte ,Valdersnes Stig ,Sengee Myagmarsuren ,Boman Kjartan
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منبع
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jordan journal of chemistry - 2007 - دوره : 2 - شماره : 2 - صفحه:105 -116
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چکیده
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The title compound is a stable chemical entity, easily prepared on a large scale using cheap chemicals. the compound is densely functionalized, and by taking advantage of the chemical properties of the various functional groups, a variety of compounds have been synthesized. some syntheses involve deprotection of the ketal moiety to form the corresponding α, β-unsaturated acetylenic ketones, which appear to react with nucleophiles in a michael fashion. this has enabled us to develop a new furan synthesis.
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کلیدواژه
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Tetraethoxybutyne; α ,β-Unsaturated acetylenic ketones; Furan; Chain elongation; Deketalization.
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آدرس
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University of Bergen, Department of Chemistry, Norway, University of Bergen, Department of Chemistry, Norway, University of Bergen, Department of Chemistry, Norway, University of Bergen, Department of Chemistry, Norway, University of Bergen, Department of Chemistry, Norway. University of Oslo, Department of Chemistry, Norway
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پست الکترونیکی
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leiv.sydnes@kj.uib.no
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Authors
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