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Kinrtics Mechanism of Oxidation of Ethanol by Tetamethyl - Ammonium Fluorochromate
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نویسنده
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Gharib F. ,Soleimani F. ,Ghammamy S.
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منبع
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پژوهش هاي كاربردي در شيمي (jarc) - 1386 - دوره : 1 - شماره : 4 - صفحه:23 -29
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چکیده
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T.he oxidation of ethanol by tetramethylammonium f1uorochromate in acidic solution was. studied using spectrophotometric technique . the reaction was arranged to be under pseudofirst-order conditions respect to the oxidant. a michaelis-menten type kinetic was observedrespect to the substr ate. the reaction is catalyzed by hydro gen ions. dependences of the reactionrates on temperature and different solvents have been studied. the solvent effect was analyzedusing kamler-taft 's and swain 's multiparametric equations. finally, a mechanism consi stent withthe observed results has been propo sed
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کلیدواژه
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Oxidation; Kinetics; Tetramethylammonium Fluorochromate
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آدرس
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shahid beheshti university, Department of Chemistry, ایران, islamic azad university, Science & Research Campus, Department of Chemistry, ایران, imam khomeini international university, Department of chemistry, ایران
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پست الکترونیکی
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f-gharib@cc.sbu.ac.ir
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Authors
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