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investigation the performance of ethylene glycol assisting prepared ceo2-cu/kit-6 catalyst in steam reforming of methanol
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نویسنده
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sadeghian vavsari mobina ,taghizadeh mazandarani majid
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منبع
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دومين كنفرانس كاتاليست انجمن شيمي ايران - 1398 - دوره : 2 - دومین کنفرانس کاتالیست انجمن شیمی ایران - کد همایش: 98191-28716 - صفحه:0 -0
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چکیده
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'ordered mesoporous silicas were first reported in 1992[1]. mesoporous silica supported cu and ce nanoparticles have been investigated for hydrogen production from methanol steam reforming[2]. three-dimensional kit-6 possessing interconnected mesopores offers superior metal dispersion[3]. ethylene glycol (eg) assisted impregnation of copper catalyst on kit-6 (ceo2-cu/kit-6 (eg)) was performed and applied for steam reforming of methanol. the catalyst was characterized by xrd, bet and tem. it is found that smaller copper particles were well dispersed on kit-6 and better catalytic activity was shown for the ceo2-cu/kit-6 (eg) when compared with the catalyst of ceor2r-cu/kit-6 prepared by using the conventional impregnation method. thebest catalytic performance was about 94.01% methanol conversion, 95.92% h2 selectivity at 300 °c.'
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کلیدواژه
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steam reforming ,ceo2-cu/kit-6 catalysts ,ethylene glycol ,impregnation
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آدرس
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, iran, , iran
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پست الکترونیکی
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omys7m@gmail.com
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Authors
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