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bimetallic nico mofs decorated on carbon felt as an binder-less anode electrode for direct ethanol fuel cell
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نویسنده
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mohammadi tahereh ,hosseini mirghasem ,ashassi sorkhabi habib
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منبع
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هجدهمين سمينار ملي الكتروشيمي ايران - 1402 - دوره : 18 - هجدهمین سمینار ملی الکتروشیمی ایران - کد همایش: 02240-27083 - صفحه:0 -0
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چکیده
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Direct ethanol fuel cells (defcs), innovative electrochemical energy conversion devices, could ease the environmental and energy crisis. the high cost of pt-based catalysts hinders the application of defcs. metal-organic frameworks (mofs) as an attractive type of porous crystalline materials (pc) have provided a unique choice for designing the distribution of metals on carbon substrates for various energy applications. here, the nico mofs were arrayed on highly conductive three-dimensional (3d) active carbon felt (acf) as supported by a simple solvothermal method. the performance of the as-prepared nico mofs/acf as a binder-less anode electrode was investigated in a single direct ethanol fuel cell. the nico-mof/acf delivered 36.8 mw cm-2 power density at 60 ̊c compared to commercial pt/c (e-tek) (9.2 mw cm-2). the structural advantages such as the 3d architecture of acf, a synergistic effect between two metals (co and ni) and many accessible active sites resulted in the magnificent activity of nico mofs/acf.
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کلیدواژه
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metal-organic framework ,carbon felt ,ethanol fuel cell ,power density
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آدرس
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, iran, , iran, , iran
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Authors
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