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bismuth ferrite/reduced graphene oxide thin film as a visible-light photocatalyst
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DOR
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20.1001.2.0021079099.1400.8.1.163.3
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نویسنده
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ghorbani m.
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منبع
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كنگره بين المللي رنگ و پوشش - 1400 - دوره : 8 - کنگره بین المللی رنگ و پوشش - کد همایش: 00210-79099 - صفحه:1 -1
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چکیده
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Bismuth ferrite/reduced graphene oxide (bgo) thin film was grown on a glass substrate via a simple sol-gel dip coating technique for photocatalytic dye degradation. the as-prepared bgo thin film was characterized by x-ray diffraction (xrd) and scanning electron microscopy (sem). xrd patterns indicate that the bgo thin film is mainly composed of a rhombohedral perovskite bfo phase with all peaks indexed to the r3c space group. sem result exhibit hierarchical porosity and spherical morphology with a uniform particle size of 25 nm. it also reveals that the matrix is uniform without any segregation of impurity phase. the photocatalytic experiment shows that bgo with 5 cm2 size can degrade methylene blue dye up to 90% in 300 min. the improvement in photocatalytic activity of the bfo by adding rgo could be ascribed to the enhanced separation efficiency of visible light-generated electron-hole pairs. the possible photocatalytic mechanism with •oh radical species as the main active species in photocatalysis was proposed.
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کلیدواژه
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bismuth ferrite ,graphene oxide ,photocatalyst ,thin film ,dip coating ,sol-gel
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آدرس
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university of tehran, college of engineering, school of metallurgy and materials engineering, iran, university of tehran, iran, university of tehran, iran, university of tehran, iran
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Bismuth ferrite/reduced graphene oxide thin film as a Visible-light photocatalyst
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Authors
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Ghorbani M.
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Abstract
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Bismuth ferrite/Reduced graphene oxide (BGO) thin film was grown on a glass substrate via a simple sol-gel dip coating technique for photocatalytic dye degradation. The as-prepared BGO thin film was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD patterns indicate that the BGO thin film is mainly composed of a rhombohedral perovskite BFO phase with all peaks indexed to the R3C space group. SEM result exhibit hierarchical porosity and spherical morphology with a uniform particle size of 25 nm. It also reveals that the matrix is uniform without any segregation of impurity phase. The photocatalytic experiment shows that BGO with 5 cm2 size can degrade methylene blue dye up to 90% in 300 min. The improvement in photocatalytic activity of the BFO by adding rGO could be ascribed to the enhanced separation efficiency of visible light-generated electron-hole pairs. The possible photocatalytic mechanism with •OH radical species as the main active species in photocatalysis was proposed.
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Keywords
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Bismuth ferrite ,Graphene oxide ,Photocatalyst ,Thin film ,Dip coating ,Sol-Gel
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