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   attenuation of incident light sources (two flow tubes in one geometrical flow cell assembly: first with eleven sources while the second is covered by six sources) in cfia for the determination of copper (ii) ion  
   
نویسنده hussein ghadah f. ,turkey nagham s.
منبع journal of medicinal and pharmaceutical chemistry research - 2021 - دوره : 3 - شماره : 11 - صفحه:763 -778
چکیده    A highly accurate, simple, sensitive and fast developed method was used for the determination of copper (ii) ion using a homemade nag-adf-300-2 system with continuous flow injection analysis system. this method is based on reaction between copper (ii) ion and rubeanic acid to obtain a black precipitate for the ion-pair complex. turbidity was measured via the attenuated of incident light by precipitated at 0-180°. optimum parameters were studied to increase the sensitivity for newly developed methodology of copper (ii) ion -rubeanic acid system. the linear range for calibration graph was 1-25 mmol.l^-1 for cell a and 1-30 mmol.l^-1 for cell b, and loq 27.0538 μg /78.5 μl for cell a and 18.5539 μg /78.5 μl for cell b respectively with correlation coefficient (r) 0.9979 for cell a and 0.9992 for cell b, rsd % was lower than 0.5%, (n=8) for the determination of copper (ii) ion at concentration 18, 23 mmol.l^-1 for cell a and 12, 19 mmol.l^-1 for cell b, respectively. a comparison was made between the newly developed method with uv-spectrophotometric method as a classical method by tow type of statistical analysis for comparison the means and variance from different methods. the comparison of data revealed that long distance chasing photometer (nag-adf-300-2) was the choice with excellent extended detection, wide application and more sensitive.
کلیدواژه attenuation of incident light; continuous flow injection analysis; white snow leds; copper (ii) ion; rubeanic acid
آدرس university of baghdad, college of science, department of chemistry, iraq, university of baghdad, college of science, department of chemistry, iraq
پست الکترونیکی nagamturkey@yahoo.com
 
     
   
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