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h2o2 as a green and environmentally benign reagent for the oxidation of sulfides in the presence of {[k.18-crown-6]x3}n (x= br, i) compared with some other organic tribromides
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نویسنده
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rasooli mohsen ,zolfigol mohammad ali ,moslemin mohammad hossien ,mohebat razieh ,chehardoli gholamabbas
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منبع
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journal of medicinal and pharmaceutical chemistry research - 2020 - دوره : 2 - شماره : 1 - صفحه:44 -50
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چکیده
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In the presence of {[k.18-crown-6]x3}n (x= br, i)-as interesting trihalide reagents, organic sulfides were oxidized to their corresponding sulfoxides using h2o2 as a green reagent. {[k.18-crown-6]x3}n activates h2o2 via in situ generation of hox and variously substituted sulfides were selectively transformed into the corresponding sulfoxides. we compared the obtained results of {[k.18-crown-6]x3}n with some other organic tribromides. unexpectedly, in most cases, the results were similar.
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کلیدواژه
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h2o2; {k.18-crown-6]br3}n; {k.18-crown-6]i3}n; oxidation; sulfides; sulfoxides
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آدرس
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islamic azad university, yazd branch, department of chemistry, iran, bu-ali sina university, faculty of chemistry, iran, islamic azad university, yazd branch, department of chemistry, iran, islamic azad university, yazd branch, department of chemistry, iran, hamedan university of medical sciences, school of pharmacy, medicinal plants and natural products research center, department of medicinal chemistry, iran
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پست الکترونیکی
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chehardoli@umsha.ac.ir
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Authors
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