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enhancing jatropha curcas seed oil-based biolubricants with metal oxide additives: synthesis, characterization, and performance evaluation
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نویسنده
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ankomah nana ,eze bright ,oguayo chukwuebuka ,afuape akinwunmi ,chimezie nathaniel ,abdullahi kasim ,bello afolabi ,ajadi abiodun ,adeyemi surajudeen ,ezeokolie ebube ,nworie justin ,adetunji sodiq ,onyishi john
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منبع
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progress in chemical and biochemical research - 2024 - دوره : 7 - شماره : 4 - صفحه:412 -429
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چکیده
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Non-edible vegetable oils have garnered significant research attention in recent years due to their enhanced tri-bological characteristics as biolubricants. jatropha curcas oil, in particular, shows promising potential as a feedstock for lubricant production. in this study, jatropha biolubricant was synthesized through a two-step transesterification process: first converting jatropha seed oil to methyl ester and then further transesterifying the methyl ester with sodium methoxide in the presence of ethylene glycol. the synthesis achieved a yield of 83.21-90% of jatropha biolubricant using sodium methoxide as the catalyst. to enhance its performance, the synthesized biolubricant was blended with copper oxide (cuo) and zinc oxide (zno) as metal additives. viscosity tests revealed that the blended biolubricant at 1 wt% additive concentration exhibited optimal viscosity characteristics: 52.952 cst at 40 ℃ and 8.767 cst at 100 ℃, compared to 31.58 cst and 6.547 cst, respectively, for the biolubricant without additives. furthermore, blended biolubricant exhibited improved thermal degradation resistance and enhanced oxidative stability across different additive concentrations. key lubricating properties such as pour point (10 ℃), viscosity at 40 ℃ (52.951 cst), viscosity at 100 ℃ (8.767 cst), and viscosity index (165.54) were analysed and found comparable to sae 40 petroleum lubricants and other plant-based biolubricants.
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کلیدواژه
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biolubricants ,jatropha ,transesterification ,methyl ester ,metal oxide
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آدرس
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kwame nkrumah university of science and technology, department of chemistry, ghana, yaba college of technology, department of mechanical engineering, nigeria, southern illinois university edwardsville, department of environmental science, usa, north carolina a&t university, department of biochemistry, usa, federal university of technology, department of environmental management, nigeria, federal university of technology owerri, department of environmental management technology, nigeria, ladoke akintola university of technology, department of chemical engineering, nigeria, university of ibadan, department of industrial and production engineering, nigeria, osun state university, department of industrial chemistry, nigeria, federal university of technology owerri, department of chemical engineering, nigeria, yaba college of technology, department of metallurgical engineering, nigeria, ladoke akintola university of technology, department of mechanical engineering, nigeria, university of nigeria, department of pharmacy, nigeria
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پست الکترونیکی
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onyishi31@gmail.com
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Authors
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