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analytical methods: electrochemical azido-selenenylation of some olefins by cyclic voltammetry and controlled-potential coulometry
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نویسنده
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rouhollahi ahmad ,asghari zeenat ,movassagh barahman
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منبع
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analytical methods in environmental chemistry journal - 2018 - دوره : 1 - شماره : 1 - صفحه:67 -74
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چکیده
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Electrochemical azido-phenylselenenylation of some olefins was studied with the oxidation of diphenyl diselenide in the presence of some olefins and sodium azide in dimethyl formamide containing tetra butyl ammonium perchlorate as supporting electrolyte in an h-type cell. the electrochemical oxidation of the mixture of (phse)2, olefins, and nan3 was studied by cyclic voltammetry and controlled-potential coulometry. anti product can be obtained with markovnikov orientation. this product was characterized .by 1h, 13c nmr, and ir spectroscopy
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کلیدواژه
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electrosynthesis ,diphenyl diselenide ,markovnikov ,cyclic voltammetry ,controlled-potential coulometry
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آدرس
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k.n. toosi university of technology, faculty of science, chemistry department, iran, k.n. toosi university of technology, faculty of science, chemistry department, iran, k.n. toosi university of technology, faculty of science, chemistry department, iran
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Authors
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