Efficient and Selective Oxidation of Hydrocarbons with tert-Butyl Hydroperoxide Catalyzed by Copper(II) UnsymmetricalSchiff Base Complex Immobilized into Mesoporous MCM-41

In this study, we investigated the effectiveness of a copper(ii)unsymmetrical schiff base complex (cul where h2l =salicylideneiminoethyliminopentane-2-one) immobilized intomesoporous silica mcm-41 in the hydroxylation of alkanes andepoxidation of alkenes through tert-butyl hydroperoxide (tbhp) asoxidant. this heterogeneous mcm-41-pr-nh2-cul catalyst exhibitedremarkable activity and selectivity in alkene epoxidation and alkanehydroxylation, producing high to excellent yields at room temperature.the catalyst could be recovered quickly through simple filtration andreused four times without considerable loss in its catalytic efficiency.furthermore, upon analyzing the fourier transform infrared (ft-ir) spectrum of the recovered catalyst and comparing it with the freshone, it was found that the structure of the catalyst remained unchanged even after the recovery process.