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Bimetallic Mofs As Catalysts For Efficient and Totally Selective Oxidation of Benzylic Alcohols At Ambient Conditions
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نویسنده
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Farrokhi Alireza ,Asaadzadeh Maryam ,Feizpour Fahimeh
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منبع
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Inorganic Chemistry Research - 2021 - دوره : 5 - شماره : 1 - صفحه:1 -9
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چکیده
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The catalytic activity of bimetallic mofs known as sta-12 (m1, m2) (m1,2 = mn, fe, co) was investigated in the oxidation of benzylic alcohols to corresponding aldehydes at ambient conditions. the oxidation reaction with na2s2o4/tbhp (tert-butyl hydroperoxide) mixture shows total selectivity and excellent efficiency under desired reaction times. the heterogeneous catalyst displays high reusability and stability for the ten consecutive reactions without decreasing in yield and selectivity. to identify radical species responsible for the oxidation process, selective scavenging experiments were performed and a purposed oxidation mechanism was discussed.
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کلیدواژه
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Heterogeneous Catalysis ,Bimetallic Mofs ,Alcohol Oxidation ,Sta-12
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آدرس
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University Of Birjand, Faculty Of Science, Department Of Chemistry, Iran, University Of Birjand, Faculty Of Science, Department Of Chemistry, Iran, University Of Birjand, Faculty Of Science, Department Of Chemistry, Iran
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پست الکترونیکی
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f_feizpour@birjand.ac.ir
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Authors
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