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plumbum(ii) and zinc(ii) complexes with 5-chlorosalicylic acid: structure and propertie
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نویسنده
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wu k.-f. ,feng y. ,jiang f. ,bai x.-l. ,yin x.-h.
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منبع
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inorganic chemistry research - 2017 - دوره : 1 - شماره : 2 - صفحه:93 -104
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چکیده
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Two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (h2l5), and 1,10-phenanthroline(phen)and 1,3-di(4-pyridyl)propane (bpp) as secondary ligands are reported, these two are formulated as {[pb(hl5)2(phen)(h2o)]·h2o}n (1), and [zn2(hl5)4(bpp)2]n (2), and are characterized by single-crystal x-ray diffraction. compoud 1 crystallizes in the triclinic p-1 space group while compoud 2 in the monoclinic system with space group c2/c. in compund 1, the carboxylate group of the coordinated hl5- adopt к^2o,o' coordination fashion to connect one pb(ii) ion but all the carboxylate groups adopt the different μ1-η^1: η^1 mode in the crystal of compoud 2 compared to 1. the solid-state photoluminescent properties at room temperature and thermal decomposition process of complexes were investigated.
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کلیدواژه
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transition metal complexes ,single-crystal x-ray diffractions ,solid-state photoluminescent properties ,thermal decomposition process
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آدرس
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guangxi university for nationalities, college of chemistry and chemical engineering, china, guangxi university for nationalities, college of chemistry and chemical engineering, china, guangxi key laboratory of chemistry and engineering of forest products, china, guangxi key laboratory of chemistry and engineering of forest products, china, guangxi university for nationalities, college of chemistry and chemical engineering, china
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پست الکترونیکی
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2386754631@qq.com;849985614@qq.com
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Authors
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