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sonochemical synthesis of novel nano flower lead(ii) metal-organic coordination polymer: a new precursor to produce nano-sized pbo
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نویسنده
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mirtamizdoust b. ,safari r. ,anbarteh s.
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منبع
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inorganic chemistry research - 2017 - دوره : 1 - شماره : 2 - صفحه:171 -182
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چکیده
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The new nano flowerpb(ii) 1dmetal-organic chain {[pb(phen)(μ-ch3coo)]·(bf4)}n(1) (phen = 1,10-phenanthroline) was synthesized by a sonochemical irradiation assisted method. the compound was characterized by scanning electron microscopy (sem), elemental analysis, ft-ir spectroscopy, x-ray powder diffraction (xrpd) and single crystal x-ray analysis. the x-ray analysis reveals a 1dchain metal-organic coordination polymer structure for 1 thatis further extended into a 3d supramolecular structure by π-π and other labile interactions. the coordination number of the lead(ii) ions is determined was abouteight, pbf2n2o4. the lead oxide nanoparticles were prepared at 180 °c by the thermolysis of 1. the average diameter of the nanoparticles to be 27 nm. the size and morphology of the prepared pbo samples were further observed using sem.
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کلیدواژه
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nanometal-organiccoordination polymer ,ultrasonicirradiation ,1dchain ,nano pbo
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آدرس
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university of qom, faculty of science, department of chemistry, iran, university of qom, faculty of science, department of chemistry, iran, university of qom, faculty of science, department of chemistry, iran
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پست الکترونیکی
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sanbarteh@gmail.com
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Authors
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