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Adsorption of Reactive Blue 19 onto Activated Carbon Prepared from Pomegranate Residual by Phosphoric Acid Activation: Kinetic, Isotherm and Thermodynamic Studies
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نویسنده
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Radaei E. ,Alavi Moghaddam M. R. ,Arami M.
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منبع
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progress in color, colorants and coatings - 2014 - دوره : 7 - شماره : 4 - صفحه:245 -257
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چکیده
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in this study, the adsorption of reactive blue 19 onto pomegranate residual-based activated carbon was investigated in aqueous solution. the activated carbon prepared by phosphoric acid activation under air condition. prac was characterized for its surface chemistry by point of zero charge measurements, scanning electron microscopy and nitrogen adsorption at 77 k. the effect of operational parameters including contact time, initial ph, adsorbent dose, initial dye concentration and particle size were studied. results showed that an optimum dye removal efficiency (96.7%) was observed at initial ph=11, contact time of 5 min, adsorbent dose of 3.25 g/l, initial dye concentration of 200 mg/l, and particle size of 63-149µm. the adsorption process was found to follow the temkin isotherm equation (r2=0.975) and second-order kinetic model (r2=0.999). furthermore, thermodynamic parameters such as ?g°, ?h°, and ?s° were calculated.
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کلیدواژه
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Adsorption ,Pomegranate residual ,Phosphoric acid ,Reactive blue 19 ,Kinetic and isotherm study ,Thermodynamic
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آدرس
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amirkabir university of technology, M Sc , Department of Civil and Environmental Engineering, Amirkabir University of Technology, P O Box: 15875-4413, Tehran, Iran , ایران, amirkabir university of technology, Associate Professor, Department of Civil and Environmental Engineering, Amirkabir University of Technology, P O Box: 15875-4413, Tehran, Iran , ایران, amirkabir university of technology, Professor, Department of Textile Engineering, Amirkabir University of Technology, P O Box: 15875-4413, Tehran, Iran , ایران
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Authors
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