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integrated simulation and improvement of the multi-bed methanol synthesis process with syngas recycling and energy recovery in aspen hysys
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نویسنده
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tavalatifi fatemeh ,sami samaneh ,bashipour fatemeh
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منبع
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iranian journal of chemical engineering - 2025 - دوره : 22 - شماره : 3 - صفحه:18 -33
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چکیده
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The synthesis of methanol is a key industrial process, but its performance is constrained by equilibrium conversion, heat dissipation, and energy inefficiencies. this study simulated the multi-bed adiabatic reactor of the methanol and derivatives complex (cp1z) located in arzew, algeria by aspen hysys. two reactor models were evaluated: the equilibrium reactor (er), based on gibbs free energy minimization, and the plug flow reactor (pfr), which incorporates detailed kinetics. both models were validated against industrial plant data to assess predictive accuracy. the er model demonstrated better agreement with industrial data, particularly for the concentration of methanol (0.36% deviation), and was therefore selected for process improvement studies. two modifications were introduced. first, recycling unreacted syngas increased the production of methanol from 613 kmol/h to 1800 kmol/h, a 193% improvement. second, replacing air coolers with a heat exchanger–steam turbine system enabled the recovery of 1100 kw of electricity without reducing the methanol yield. when both modifications were applied simultaneously, the methanol output rose to 1917 kmol/h (+213%), and electricity generation increased to 1763 kw. the integration of the recycling of syngas and waste heat recovery substantially enhances the conversion efficiency, energy utilization, and sustainability of the production of methanol. since these modifications require no major hardware changes, they offer a practical and scalable strategy for improving the technical, economic, and environmental performance of existing industrial methanol plants.
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کلیدواژه
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aspen hysys ,methanol synthesis ,multibed reactor ,energy recovery ,quenching
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آدرس
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razi university, faculty of petroleum and chemical engineering, iran, technical and vocational university (tvu), faculty of engineering sciences, department of engineering sciences, iran, razi university, faculty of petroleum and chemical engineering, iran
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پست الکترونیکی
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f.bashipour@razi.ac.ir
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Authors
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