ammonia decomposition for hydrogen production in catalytic microchannels with slip/jump effects

The rarefaction effects on the catalytic decomposition of nh3 in ruthenium–coated planar microchannels is numerically simulated in the knudsen number range 0.015-0.03. a colocated finite–volume method is used to solve the governing equations. a concentration jump model derived from the kinetic theory of gases is employed to account for the concentration discontinuity at the reactive walls. a detailed surface reaction mechanism for ammonia decomposition on ruthenium along with a multi-component species diffusion model are used to study the effects of concentration jump coupled with velocity slip and temperature jump on the walls. the velocity-slip, temperature-jump and concentration-jump boundary conditions have miscellaneous effects on flow, temperature and species concentration fields. the results suggest that the velocity-slip boundary condition only slightly influences the species distribution at the edge of the knudsen layer as well as inside the channel, while the temperature-jump boundary condition affects the heat and mass transfer characteristics the most. the concentration-jump effect, on the other hand, can counter balance the temperature-jump effects in some cases.