Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives

Acetylenic amine derived from secondary amines such as piperidine , pyrolidine and diethyl amine were synthesized as charge transfer donor have been treated with receptor i2,br2 and ddq (ddq = 2,3-dichloro-5,6-dicyano-p-benzoquinone) to prepare transitional charge complexes .benesi-heldbrand equation have been used at (λmax)for formation complexes to calculate potentialionize. calculation for acetylenic amines derivatives at the first time from transitional energy withstudied receptor and calculated equilibrium constant.