|
|
|
|
Synthesis of New Diazahomoadamantanone and Study the Reactivity of Carbonyl group
|
|
|
|
|
|
|
|
نویسنده
|
Shukkur Ahmad H. ,Kuznetsov A. I. ,Serova T. M.
|
|
منبع
|
journal of university of anbar for pure science - 2011 - دوره : 5 - شماره : 3 - صفحه:- --
|
|
چکیده
|
In this paper, new diazahomoadamantane was prepared by condensation of cyclic ketone (cyclododecanone) with 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane and acetic acid in 2-propanol gave new diazahomoadamantanone (13,16-diazatetracyclo-[9.6.1.11,13.111,16]eicosan-18-one) by mannich,s reaction. also were studied the reactivity of carbonyl group with various chemical agents like ( nabh4 , h2n-nh2.h2o and nh2-oh.hcl). a simplified procedure was developed for the synthesis of 1,3,6,8-tetraazatricyclo [4.4.1.13,8]dodecane from condensation of ethane-1,2-diamine with paraform (type a) in a very good yield. this new compound was characterized by ft-ir, mass spectrum, 1h nmr and 13c nmr spectroscopy methods.
|
|
کلیدواژه
|
Mannich reaction ,Ethane-1 ,2-diamine ,Paraformaldehyde ,yclododecanone ,Diazahomoadamantanone.
|
|
آدرس
|
University of Al-Anbar, College of Education for Pure Sciences, Iraq, Lomonosov Academy of Fine Chemical Engineering, Russia, Institute of Physiologically Active Substances, Russian Academy of Science, Russia
|
|
پست الکترونیکی
|
ahmedsatori@yahoo.com
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Authors
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|