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Effect of Textural Properties of Y, ZSM-5 and Beta Zeolites on Their Catalytic Activity in Catalytic Cracking of a Middle Distillate Cut Named RCD
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نویسنده
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mirshafiee faezeh ,karimzadeh ramin ,khoshbin reza
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منبع
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journal of oil, gas and petrochemical technology - 2021 - دوره : 8 - شماره : 2 - صفحه:60 -74
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چکیده
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In the present study, the performance of three catalysts containing y, zsm- 5 and beta zeolite in the catalytic cracking of a kind of middle distillate cut named ”rcd” has been studied. the catalysts were characterized by xrd, ftir, sem, n2 adsorption/ desorption and nh3-tpd techniques. furthermore, deactivated catalysts in terms of type and amount of deposited coke were analysed. results of catalytic tests showed that y zeolite performed better and it decreased viscosity and density of liquid product by 35% and 3% respectively. this good operating was due to the high surface area (812m2/gr) and higher acidic sites amounts (1.8 mmol nh3/gr) which gives the heavy molecules better accesibility to active acid sites. but more cokes have deposited on y zeolite which was 50% lower for beta and zsm-5 zeolites. finally, it can be concluded that the ultimate performance of catalysts in catalytic cracking is influenced by the synergetic effects between the pore structure and acidity.
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کلیدواژه
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Catalytic cracking ,heavy hydrocarbons ,zeolite Y ,zeolite Beta ,Zeolite ZSM-5
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آدرس
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tarbiat modares university, faculty of chemical engineering, Iran, tarbiat modares university, faculty of chemical engineering, Iran, imam khomeini international university, buin zahra higher education center of engineering and technology, Iran
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پست الکترونیکی
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r.khoshbin@bzeng.ikiu.ac.ir
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Authors
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