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   silver doped tio2 nanoparticles: preparation, characterization and efficient degradation of 2,4-dichlorophenol under visible light  
   
نویسنده sarteep zahra ,ebrahimian pirbazari azadeh ,aroon mohammad ali
منبع journal of water and environmental nanotechnology - 2016 - دوره : 1 - شماره : 2 - صفحه:135 -144
چکیده    Hydrothermally synthesized tio2 nanoparticles containing different amounts of silver were characterized by x-ray diffraction (xrd), fourier transform infrared (ft-ir) and scanning electron microscopy equipped with energy dispersive x-ray microanalysis (sem/edx) techniques. xrd results showed prepared samples include 100% anatase phase. the presence of silver in tio2 nanoparticle network was established by xrd, sem/edx and ft-ir techniques. the photocatalytic performance of the prepared catalysts was tested for the degradation of 2,4-dichlorophenol (2,4-dcp) under visible light.. the experiments demonstrated that 2,4-dcp was effectively degraded in the presence of ag/tio2 samples. it was confirmed that the presence of ag on tio2 catalysts could enhance the photocatalytic degradation of 2,4-dcp in aqueous suspension. it was found that an optimal dosage of 1.68 wt% ag in tio2 achieved the fastest 2,4-dcp degradation (95% after 180 min irradiation) under the experimental conditions. on the basis of various characterizations of the photocatalysts, the reactions involved to explain the photocatalytic activity enhancement due to ag doping include a better separation of photogenerated charge carriers. gc-ms analysis showed the major intermediates of 2,4-dcp degradation are simple acids like oxalic acid, acetic acid, etc. as the final products.
کلیدواژه 4-dichlorophenol ,degradation ,silver ,tio2
آدرس university of tehran, college of engineering, fouman faculty of engineering, ایران, university of tehran, college of engineering, fouman faculty of engineering, caspian faculty of engineering,, ایران, university of tehran, college of engineering, caspian faculty of engineering, ایران
 
     
   
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