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   nano-sio2 modified by ctab and oxime ligand for separation and preconcentration of trace amount of cu(ii) in real environmental samples  
   
نویسنده vaezi narges ,dalali nasser ,hosseini mehdi
منبع iranian journal of analytical chemistry - 2017 - دوره : 4 - شماره : 1 - صفحه:59 -66
چکیده    A simple, novel, accurate and selective method for the determination of trace amounts of cu2+ ions in water and soil samples is proposed. the method is based on the separation and preconcentration of cu2+ on a nanosio2 modified by a cetyltrimethylammonium bromide as surfactant and indane1,2,3trione1,2dioxime as complexing agent. the retained copper on the nanosorbent was eluted with 1.5 ml of 1.0 mol l1 hno3 and measured by flame atomic absorption spectrometry. the synthesis of this nanosorbent is also described and certified by ftir, xrd and tem techniques. furthermore, several effective analytical parameters were evaluated and optimized. under the best optimum conditions maximum absorption capacity, enrichment factor and limit of detection were 7.04 mg g1, 333.3 and 4.4 µg l1, respectively. the relative standard deviation of the preconcentration method was 0.28% (n=7) and calibration curve gave good level of linearity with correlation coefficient value 0.997. finally, the feasibility and performance of the method was evaluated by determination of copper (ii) ions in several water and soil samples with satisfied results.
کلیدواژه nano-sio2 modified ,cetyltrimethylammonium bromide surfactant ,indane ligand ,separation ,preconcentration ,copper determination
آدرس university of zanjan, faculty of sciences, department of chemistry, fia-lab , ایران, university of zanjan, faculty of sciences, department of chemistry, fia-lab , ایران, university of zanjan, faculty of sciences, department of chemistry, fia-lab , ایران. university of applied-science, branch of calcimin, ایران
پست الکترونیکی mehdi.hosseini.znu@gmail.com
 
   نانو سیلیکای اصلاح‌شده توسط CTAB و لیگاند اکسیم جهت جداسازی و پیش‌تغلیظ مقادیر ناچیز یون مس (II) در نمونه‌های زیستمحیطی حقیقی  
   
Authors واعظی نرگس ,دلالی ناصر ,حسینی مهدی
  
 
 

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