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Synthesis and Characterization of Some Bis-1,3 Oxazepine - 4,7- dione and 1, 3 – Diazepine -4,7- dione Derivatives
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نویسنده
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jasim saad salim
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منبع
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kirkuk university journal: scientific studies - 2018 - دوره : 13 - شماره : 2 - صفحه:149 -165
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چکیده
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In this study, some of the new compounds have been synthesized including some of different schiff bases (1-6) via the reaction of phenyl-1,4-diamine with substituted benzaldehyde in absolute ethanol and converted into derivatives of 1,3-oxazepine-4,7-dione (7-12) via ring closure reaction [2+5] of schiff bases with maleic anhydride in dry benzene then the 1, 3- oxazepine -4, 7- compounds (7-12) were reacted with phenylhydrazine to produce 1,3-diazepine-4,7-dione (13-18). the prepared compounds were characterized by determination of melting point, ft-ir and uv-visspectra, and some of the prepared compounds have been characterized by (1h-nmr& c.h.n.) techniques.
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کلیدواژه
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Schiff bases ,3-Oaxzpine-4 ,7-dione ,3-Diazepine-4 ,7-dione
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آدرس
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university of kirkuk, college of education for pure sciences, chemistry department, Iraq
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پست الکترونیکی
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saad9228@yahoo.com
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Authors
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