بررسی ردپای طبیعت در نهشته‌های گیاهی یک انبیق شیشه‌ای هزار ساله، به روش کروماتوگرافی گازی کوپل شده با طیف‌سنج جرمی (gc-ms)

یکی از ظروف شیشه ای دوران اسلامی، ظروفی با بدن استکانی میان باریک یا گلابی شکل با کف گرد هستند و آبریز بلند لوله ای شکل دارند که کمتر شناخته و مطالعه شده اند. سه کاربرد برای این گونه ظروف پیشنهاد شده است. بادکش یا شاخ حجامت در پزشکی، انبیق در آزمایش های شیمیایی یا کیمیاگری و یا ظرفی که در داروسازی و تولید مواد آرایشی و عطرسازی، برای ترکیب مواد و انتقال از طریق لوله آن به دارو دان یا عطر دان یا ظرف ویژه مواد آرایشی به کار می رفته است. به نظر می رسد که اگر ظرف از دهانه، بر زمین نهاده شود و لوله آن در جهت مخالف بدنه، به طور کامل، به بالا خمیده و بلندتر از بدنه باشد، می توان کاربرد آن را بادکش یاشاخ حجامت و یا ظرف ترکیب دارو، مواد آرایشی و عطر، پیشنهاد کرد و اگر لوله آن کاملا کشیده و عمود به بدنه و یا اندکی خمیده باشد، می توان هر سه کاربرد یادشده را برای آن فرض کرد. تا حدودی، شرح و تصاویر متون دوره اسلامی در شناخت کاربرد این ظروف راهگشا هستند. از آنجاکه تاکنون به ویژه در ایران، هیچ گاه نوشته های درون چنین ظروفی، تجزیه و تحلیل نشده تا عملا روشن شود چه کاربردی داشته اند، برای نخستین بار، این فرآیند در مورد یکی از این گونه ظروف که دارای لوله کشیده است و در مخزن موزه آبگینه ها و سفالینه های ایران نگهداری می شود، با روش کروماتوگرافی گازی کوپل شده با طیف سنج جرمی ( gc- ms ) انجام گرفت که موفق به ردیابی بقایای مواد طبیعی نظیر تیمول و کارواکرول شد که این مواد از اجزا اصلی تشکیل دهنده اسانس های طبیعی نظیر آویشن و مرزه هستند و در بسیاری از عرقیجات قابل تشخیص هستند، این ظرف، به احتمال زیاد به عنوان انبیق برای تقطیر و استخراج مواد فرار گیاهی و روغنی در داروسازی، تولید مواد آرایشی و عطرسازی، به کار رفته است.

Study of the traces of nature in herbal deposits of a thousand-year-old Alembic glass analyzed and processed by the Gas Chromatography-Mass Spectrometer (GC-MS).

During the Islamic periods, the containers characterized by narrow or pearshaped glassbody with a round bottom and long drainage pipe or tube were known, but rarely have been studied. There are three different hypotheses for applications of such containers. A cupping glass(Shakhi hajamat) for phlebotomize in medicine, ldquo;Alembic rdquo; for chemical or alchemical experiments, or containers for pharmaceuticals and the production of cosmetics and perfumes which has been used for making the materials and transfer them through tubes, or perfume containers as particular container for cosmetics. It seems that if the container is placed from the opening on a surface, then its pipe is wholly bent in the opposite direction of the body. Where it is taller than the body, it could be used or applied as a cupping glass for phlebotomize in medicine or as a container for materials in medications, cosmetics and perfumery. If the pipe is entirely straight and perpendicular to the body or slightly curved, it could be used for all three applications mentioned above. In Islamic periods, the Arabic word of KIMIA (elixir) was synonymous with alchemy and chemistry in the viewpoint of technology and therefore, includes a variety of processes, including distillation of herbs and medicinal oils, perfumes and rosewater, and fragrant oils and other substances. Some of tools and equipment used for alchemy have been made of glass like the distiller. There have been many pacts for using these kinds of container in the Islamic literature written by Abu Musa Jaber Ibn Hayyan (Around 721 to 815 AD) and Abū Bakr Muhammad ibn Zakariyyā alRāzī (865 to 923 AD) who were known as the greatest scientists in the history of chemistry and chemical technology in the Islamic world. Their scientific and practical works have had a great impact on the scientists and researchers of the next generations, both Muslims and Europeans. Many methods, such as distillation and all kinds of basic related tools, such as Cucurbit (qar rsquo;a) and Alembic (alinbīq) have been attributed to Jabir Ibn Hayyan. However, alRazi in his book, Kitab alasrar or Secret of alchemy, among the tools and devices for chemical processing (Tadbir) and distillation (Taqtir), has mentioned to them and studied the Cucurbit and Alembic with an outlet pipe, a distilled liquid container, recipient (qabila) and a blind Alembic (without an outlet pipe) (anbiq alchr('39')aemaa). As a matter of fact, the chemical composition of materials inside such containers discovered in Iran has not yet been studied, while it is a critical issue for the characterization and application of these containers. For the first time, one of such containers with a long and straight tube which was kept in the Glassware and Ceramic Museum of Iran has been analyzed and processed by the Gas ChromatographyMass Spectrometry (GCMS) technique. The analysis of chemical compounds detected in this container revealed that it had been exposed to essential, and natural oils for a long time. The GCMS analysis of the washing solution led to the identification of 22 substances, where the main identified compounds were: thymol, carvacrol, pcymene and gamma;terpinene, fatty acids (palmitic acid and stearic acid), and a significant number of substances of the waxes groups. Thymol and carvacrol are the main substances of natural essential oils of Thyme, Savory and Marjoram. Also, the findings of this research have proved the contact of the abovementioned container with natural essential oils, especially thyme. The ingredients found in this container could be recognizable in many distillates. So, it can suggest that the container has been used as an Alembic for distillation and extraction of vegetable and volatile oil substances in pharmacy, cosmetics and perfumes. More analysis in the future on the contaminated materials within such containers can give more clues and advantages for clarifying the more possible application of these containers.