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   removal of cadmium from aqueous solution using nano prosopis cineraria leaf ash (npcla)  
   
نویسنده pourjaafar milad ,askari ali ,salehi sahl abadi ali ,anvaripour bagher ,nemati afshar ,rahimi ali ,pourjafar mona
منبع environmental health engineering and management journal - 2023 - دوره : 10 - شماره : 2 - صفحه:225 -233
چکیده    Background: heavy metal pollution has become one of the most severe environmental problems, therefore, the present study was conducted to investigate removal of cadmium (cd) from aqueous solution.methods: in the present study, nano prosopis cineraria leaf ash (npcla) was used as an adsorbent for removing cd from aqueous solution. contact time, initial ph of the solutions, sorbent dosages, and initial cd (ii) concentration were considered as parameters affecting cd removal efficiency. the experiments were designed by design of expert (doe) software.results: it was revealed that an npcla dosage of 2.45 gl-1, ph of 6.3, and initial cd (ii) concentration of 20.7 mgl-1 in contact time of 60 min was the optimum condition for removal of cd (ii) in the domain of experiments and at this optimum condition, the prediction value of removal efficiency was found 99.9%. based on the results of kinetics experiments, the sorption system and experiment data of cd (ii) adsorption on the npcla followed the pseudo-second-order kinetic model. freundlich, langmuir, brunauer-emmett-teller (bet), and temkin isotherm models were investigated. the equilibrium adsorption data were fitted well with linearly transformed langmuir isotherm with a correlation coefficient of r2 = 0.9877, and the maximum sorption capacity of npcla was obtained to be 25.25 mgg-1.conclusion: in laboratory conditions, npcla can remove cd from aqueous solution with a high efficiency. therefore, due to this plant’s availability and cheapness, npcla can be considered a suitable option for producing adsorbents on industrial scales.
کلیدواژه cadmium ,hydrogen-ion concentration ,nanostructure ,plant leaves ,kinetics
آدرس abadan institute of technology, department of chemical engineering- hse, hse manager department, iran. department, north azadegan oilfield project, iran, tehran university of medical sciences, school of public health, department of occupational health, iran. azar oilfield project, oico hse department, iran, shahid beheshti university of medical sciences, school of public health and safety, corresponding author: department of occupational health and safety engineering, iran, abadan institute of technology, department of chemical engineering- hse, hse manager department, iran. north azadegan oilfield project, hse manager department, iran, oico azar oilfield development site manager, azar oilfield project, iran, abadan institute of technology, department of chemical engineering- hse, iran. north azadegan oilfield project, hse manager department, iran, abadan institute of technology, department of chemical engineering- hse, hse manager department, iran. north azadegan oilfield project, hse manager department, iran
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