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Ring-opening of oxiranes using Taeniolite-supported tris(β-diketonato)zirconium
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نویسنده
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permana y. ,ichikuni n. ,shimazu s.
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منبع
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journal of mathematical and fundamental sciences - 2012 - دوره : 44 A - شماره : 3 - صفحه:263 -274
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چکیده
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A series of tris(β-diketonato)zirconium(iv) complexes was immobilized into a synthetic clay structure of taeniolite by an ion-exchange method to generate organic/inorganic hybrid compounds. the hybrid compound served as a good catalyst for ring-opening reactions of methyl,ethyl,and dimethyl oxiranes with various alcohols to generate primary alkoxy alcohols in appreciable selectivity. this method describes a technique to immobilize cationic zirconium complexes without losing selectivity. © 2012 published by lppm itb.
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کلیدواژه
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β-alkoxyalcohols; Oxiranes; Ring-opening; Taeniolite; Tris(βdiketonato)zirconium
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آدرس
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inorganic and physical chemistry research division,institut teknologi bandung,jl. ganesha 10,bandung, Indonesia, department of applied chemistry and biotechnology,chiba university,1-33 yayoi,inage, Japan, department of applied chemistry and biotechnology,chiba university,1-33 yayoi,inage, Japan
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Authors
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