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Reduction of carbonyl compounds to their corresponding alcohols by (Nicotine)(tetrahydroborato)zinc complex as a new stable and efficient reducing agent
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نویسنده
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setamdideh d. ,rafigh m.
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منبع
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journal of chemistry - 2012 - دوره : 9 - شماره : 4 - صفحه:2338 -2345
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چکیده
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(nicotine)(tetrahydroborato)zinc complex,[zn(bh 4) 2 (nic)],as a stable yellow solid,was prepared quantitatively by complexation of an equimolar amount of zinc tetrahydroborate and nicotine at room temperature. this reagent can easily reduce variety of carbonyl compounds such as aldehydes,ketones,acyloins and α-diketones to their corresponding alcohols in good to excellent yields. reduction reactions were performed in ch 3cn at room temperature. © 2012 hindawi publishing corporation.
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کلیدواژه
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Carbonyl Compounds; Nicotine; Reduction; Zn(BH 4) 2
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آدرس
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department of chemistry,mahabad branch,islamic azad university,mahabad, ایران, department of chemistry,mahabad branch,islamic azad university,mahabad, ایران
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Authors
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