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Bonding,structure,and stability of [ (N a) n (P h e) m ] n + clusters: Some surprising results from an experimental and theoretical investigation in gas phase
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نویسنده
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caetano m.s. ,ramalho t.c. ,vieira t.g. ,gonçalves a.d.s. ,mancini d.t. ,da cunha e.f.f.
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منبع
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journal of chemistry - 2013 - دوره : 2013 - شماره : 0
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چکیده
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Structure and stability of [ (n a) n (p h e) m ] n + clusters in the ground state were analyzed at the theoretical and experimental levels. our experimental and theoretical findings showed that the [ (n a) n (p h e) m ] n + clusters in gas phase tend to form mainly planar rings of four members. the symmetry and the small dipole moment in these specific configurations suggested that their stability could be associated with an alignment of the water molecules,maximizing attractive electrostatic interactions caused by changes in the charge distribution of the clusters. © 2013 melissa s. caetano et al.
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آدرس
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department of chemistry,federal university of lavras,campus universitário,37200-000 lavras, Brazil, department of chemistry,federal university of lavras,campus universitário,37200-000 lavras, Brazil, unilavras - centro universitário de lavras,rua padre josé poggel 506,centenário, Brazil, chemistry department,federal institute of education science and technology,estrada da tartaruga s/n,29215-090 bairro muquiçaba,guarapari, Brazil, department of chemistry,federal university of lavras,campus universitário,37200-000 lavras, Brazil, department of chemistry,federal university of lavras,campus universitário,37200-000 lavras, Brazil
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Authors
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