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Synthesis and crystal structure of 1-(4-Nitrobenzyl)-3-allyl-1H-benzo[d] imidazol-2(3H)-one
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نویسنده
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belaziz d. ,luis s.v. ,kandri rodi y. ,martí i. ,martí-centelles v.
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منبع
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journal of chemistry - 2013 - دوره : 2013 - شماره : 0
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چکیده
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A functionalized benzimidazole,1-(4-nitrobenzyl)-3-allyl-1h-benzo[d] imidazol-2(3h)-one,has been synthesized,and the crystal structure was determined and analyzed. this compound crystallizes in the monoclinic,space group p21/n (number 14) c with cell parameters,a = 7.12148 (8) å,b = 16.12035 (17) å,c = 13.04169 (17) å,β = 93.3043 (11),v = 1494.71 (3) å 3,and d calc = 1.375 g/mm3. the solid state geometry is stabilized by intermolecular π - π interactions along with the van der waals interactions which contribute to the stability of the crystal packing. computational calculations have been used to properly understand the main intermolecular interactions present in the crystal. © 2013 dounia belaziz et al.
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آدرس
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laboratoire de chimie organique appliquée,faculté des sciences et techniques,université sidi mohamed ben abdallah, Morocco, universitat jaume i,departamento de química inorgánica y orgánica,avenida sos baynat,s/n, Spain, laboratoire de chimie organique appliquée,faculté des sciences et techniques,université sidi mohamed ben abdallah, Morocco, universitat jaume i,departamento de química inorgánica y orgánica,avenida sos baynat,s/n, Spain, universitat jaume i,departamento de química inorgánica y orgánica,avenida sos baynat,s/n, Spain
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Authors
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