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Reaction of Acyl Chlorides with in Situ Formed Zinc Selenolates: Synthesis of Selenoesters versus Ring-Opening Reaction of Tetrahydrofuran
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نویسنده
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bellino g. ,scisciani m. ,vargas j.p. ,sancineto l. ,bagnoli l. ,marini f. ,lüdtke d.s. ,lenardao e.j. ,santi c.
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منبع
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journal of chemistry - 2016 - دوره : 2016 - شماره : 0
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چکیده
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Attempting to apply the in situ production of phseznseph to the synthesis of selenoesters,an unexpected reaction involving the solvent (tetrahydrofuran) was observed and studied. we reported here some evidences about the mechanism and the possibility to control the chemoselectivity of this new reaction that afforded the formation of interesting selenoderivatives in which the selenium moiety and the carboxylic one are spaced by four carbon units. © 2016 gemma bellino et al.
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آدرس
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group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy, group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy, instituto de química,universidade federal do rio grande do sul (ufrgs),avenida bento gonçalves 9500,porto alegre,rs, Brazil, group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy, group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy, group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy, instituto de química,universidade federal do rio grande do sul (ufrgs),avenida bento gonçalves 9500,porto alegre,rs, Brazil, laboratório de síntese orgânica limpa (lasol),centro de ciências químicas,farmacêuticas e de alimentos (ccqfa),universidade federal de pelotas (ufpel),p.o. box 354,pelotas,rs, Brazil, group of catalysis and organic green chemistry,department of pharmaceutical sciences,university of perugia,via del liceo 1,perugia, Italy
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Authors
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