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Synthesis of a one-dimensional coordination polymer of nickel(II) complex with a β-oxodithioester ligand
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نویسنده
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rosas-reyes r. ,reyes-ortega y. ,morales-juarez t.j. ,gómez-vidales v. ,garcía-orozco i.
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منبع
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journal of chemistry - 2017 - دوره : 2017 - شماره : 0
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چکیده
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Bis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-o,s]nickel(ii) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (cpdt) and ni(ii),and catena-[(μ2-4,4′-bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-o,s)]nickel(ιι) 2 was prepared in good yields from 1 plus 4,4′-bipyridyl (bpy) by shish-kebab methodology. the structure of 1 was confirmed by ftir,elemental analysis,1h nmr,uv-vis in chloroform solution and in solid,xps,and pxrd. compound 2 was characterized by ftir,elemental analysis,uv-vis in chloroform solution,and in solid,xps,pxrd,esr,and solid state magnetization measurements. the structure of the polymer was established mostly by pxrd,esr,and magnetization. © 2017 ricardo rosas-reyes et al.
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آدرس
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laboratorio de investigación y desarrollo de materiales avanzados (lidma),facultad de química,universidad autónoma del estado de méxico,carretera toluca-atlacomulco km 14.5,unidad san cayetano,toluca, Mexico, centro de química,icuap,benemérita universidad autónoma de puebla,puebla, Mexico, facultad de química,universidad autónoma del estado de méxico,paseo colón esq. paseo tollocan s/n,toluca, Mexico, instituto de química,universidad nacional autónoma de méxico,circuito interior,ciudad universitaria,coyoacán,mexico city, Mexico, laboratorio de investigación y desarrollo de materiales avanzados (lidma),facultad de química,universidad autónoma del estado de méxico,carretera toluca-atlacomulco km 14.5,unidad san cayetano,toluca, Mexico
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Authors
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