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Chemical separation on silver nanorods surface monitored by TOF-SIMS
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نویسنده
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petruš o. ,oriňak a. ,oriňaková r. ,muhmann c. ,macko j. ,hrdý r. ,hubálek j. ,erdelyi b. ,arlinghaus h.f.
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منبع
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journal of chemistry - 2017 - دوره : 2017 - شماره : 0
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چکیده
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The article introduces a possible chemical separation of a mixture of two compounds on the metal nanorods surface. a silver nanorods surface has been prepared by controlled electrochemical deposition in anodic alumina oxide (aao) template. rhodamine 6g and 4-aminothiophenol have been directly applied to the sampling point on a silver nanorods surface in an aliquot mixture. the position of the resolved compounds was analysed by time-of-flight secondary ion mass spectrometry (tof-sims) which measured the fragments and the molecular ions of the two compounds separated on the silver nanorods surface. rhodamine 6g has been preconcentrated as 1.5 mm radial from the sampling point while 4-aminothiophenol formed a continuous self-assembled monolayer on the silver nanorods surface with a maximum molecular ion intensity at a distance of 0.5 mm from the sampling point. the separation of the single chemical components from the two-component mixture over the examined silver nanostructured films could clearly be shown. a fast separation on the mentioned nanotextured films was observed (within 50 s). this procedure can be easily integrated into the micro/nanofluidic systems or chips and different detection systems can be applied. © 2017 ondrej petruš et al.
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آدرس
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faculty of sciences,department of physical chemistry,university of p. j. šafárik in košice,moyzesova 11,košice, Slovakia, faculty of sciences,department of physical chemistry,university of p. j. šafárik in košice,moyzesova 11,košice, Slovakia, faculty of sciences,department of physical chemistry,university of p. j. šafárik in košice,moyzesova 11,košice, Slovakia, westfälische wilhelms-universität münster,physikalisches institut,münster, Germany, faculty of sciences,department of physical chemistry,university of p. j. šafárik in košice,moyzesova 11,košice,slovakia,faculty of science,department of physical chemistry,comenius university,mlynská dolina ii,bratislava, Slovakia, six center,faculty of electrical engineering and communication,brno university of technology,technická 3058/10,brno, Czech Republic, six center,faculty of electrical engineering and communication,brno university of technology,technická 3058/10,brno, Czech Republic, faculty of sciences,department of physical chemistry,university of p. j. šafárik in košice,moyzesova 11,košice,slovakia,institute of physics,faculty of sciences,university of p. j. šafárik in košice,park angelinum,košice, Slovakia, westfälische wilhelms-universität münster,physikalisches institut,münster, Germany
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Authors
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