the ability of ncp@pocl2-x core-shell magnetic nano-catalyst for simultaneous conversion of epoxides into cyanohydrin and α,β-unsaturated carboxylic acid

This paper presents a new environmental, and remarkably efficient heterogeneous magnetic nanocomposite, ncp@pocl2-x (fe3o4@sio2@cs@pocl2-x), designed for the regioselective production of cyanide compounds from epoxides using nacn, subsequently facilitating the synthesis of α,β-unsaturated carboxylic acids. the reactions were conducted under mild conditions, demonstrating the catalyst’s remarkable performance with high yields. the presence of pocl2-x and the influence of water and heat facilitated the transformation of epoxides into cyanohydrin and α,β-unsaturated carboxylic acids. remarkably, the reactions demonstrate excellent regioselectivity, producing clean and quantitative products. ncp@pocl2-x is a heterogeneous magnetic nanocatalyst with a strong magnetic core of fe3o4 surrounded by chitosan as a green layer and functionalized by the pocl2-x group. this catalyst can be easily separated using external magnetic force. the combination of heterogeneity, magnetic properties, easy recovery, and exceptional performance establishes ncp@pocl2-x as a valuable tool for efficient and selective transformations of epoxides.