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photocatalytic degradation of methylene blue from aqueous solution using fe3o4@sio2@ceo2 core-shell magnetic nanostructure as an effective catalyst
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نویسنده
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ziaadini fatemeh ,mostafavi ali ,shamspur tayebeh ,fathirad fariba
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منبع
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advances in environmental technology - 2019 - دوره : 5 - شماره : 2 - صفحه:127 -132
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چکیده
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In the present study, the coreshell magnetic nanostructure of fe3o4@sio2@ceo2 was synthesized to investigate its use as an effective photocatalyst for methylene blue removal. the prepared samples were characterized by xray diffraction (xrd), transmission electron microscopy (tem), and a vibrating sample magnetometer (vsm). the photocatalytic activity for the fe3o4@sio2@ceo2 coreshell magnetic nanostructure was investigated under visible light by determining the degradation rate of methylene blue for 50 min. at the end of the photocatalytic degradation process, the magnetic catalyst was recovered by an external magnetic field. the performance of the proposed catalyst for the degradation of methylene blue was improved with the optimization of the effective parameters such as the amount of catalyst, ph, and reaction time. under optimum conditions, the efficiency of methylene blue removal with the proposed photocatalyst remains higher than 92 % after five times of use. the second pseudomodel was selected as the kinetic model to calculate catalytic degradation. the present results show that the fe3o4@sio2@ceo2 can be an efficient nanocatalyst for the photodegradation of dye pollutants.
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کلیدواژه
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core-shell magnetic nanostructure ,photodegradation ,visible light driven ,methylene blue
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آدرس
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shahid bahonar university of kerman, faculty of science, department of chemistry, iran, shahid bahonar university of kerman, faculty of science, department of chemistry, iran, shahid bahonar university of kerman, faculty of science, department of chemistry, iran, graduate university of advanced technology, department of nanotechnology, iran
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پست الکترونیکی
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f_fathirad@yahoo.com
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Authors
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