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study of ziegler-natta/(2-phind)2zrcl2 hybrid catalysts performance in slurry propylene polymerization
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نویسنده
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nejabat gholam-reza ,nejabat gholam-reza ,nejabat gholam-reza ,nekoomanesh mehdi ,arabi hassan ,salehi-mobarakeh hamid ,zohuri gholam-hossein ,mortazavi mohammad-mahdi ,ahmadjo saeid ,miller stephen a.
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منبع
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polyolefins journal - 2015 - دوره : 2 - شماره : 2 - صفحه:73 -87
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چکیده
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Several types of hybrid catalysts are made through mixing of 4th generation zieglernatta (zn) and (2phind)2zrcl2metallocene catalysts using triethylaluminum (tea) as coupling agent. response surface methodology (rsm)is used to evaluate the interactive effects of different parameters including amounts of metallocene and tea andtemperature on metallocene loading. analyzing the amounts of al and zr elements in the hybrid catalysts throughicpoes and edxa reveals that temperature plays a crucial role on anchoring of the metallocene catalyst on znwhile tea has the least determining effect. the icp analysis shows that as the concentration of al goes up in thehybrid catalyst the concentration of zr passes a maximum, while edxa shows a direct relationship between the aland zr contents. using triisobutylaluminum (tiba) and methylaluminoxane (mao) as the coupling agents, almostsimilar metallocene loadings are observed. finally, the performance of hybrid catalysts is investigated in propylenepolymerization and the obtained polymers are characterized using dsc and dmta through which the presence of twotypes of polymers in the final product are confirmed.
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کلیدواژه
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hybrid catalysts ,ziegler-natta ,metallocene ,surface and bulk analysis ,polypropylene
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آدرس
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islamic azad university, shiraz branch, school of chemical and material engineering, department of polymer engineering, ایران. iran polymer and petrochemical institute (ippi), polymerization engineering department , ایران. university of florida, department of chemistry, george and josephine butler polymer research laboratory, usa, islamic azad university, shiraz branch, school of chemical and material engineering, department of polymer engineering, ایران. iran polymer and petrochemical institute (ippi), polymerization engineering department , ایران. university of florida, department of chemistry, george and josephine butler polymer research laboratory, usa, islamic azad university, shiraz branch, school of chemical and material engineering, department of polymer engineering, ایران. iran polymer and petrochemical institute (ippi), polymerization engineering department , ایران. university of florida, department of chemistry, george and josephine butler polymer research laboratory, usa, iran polymer and petrochemical institute (ippi), polymerization engineering department, ایران, iran polymer and petrochemical institute (ippi), polymerization engineering department, ایران, iran polymer and petrochemical institute (ippi), polymerization engineering department, ایران, ferdowsi university of mashhad, faculty of science, department of chemistry, ایران, iran polymer and petrochemical institute (ippi), polymerization engineering department, ایران, iran polymer and petrochemical institute (ippi), polymerization engineering department, ایران, university of florida, department of chemistry, george and josephine butler polymer research laboratory, usa
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پست الکترونیکی
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miller@chem.ufl.edu
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Authors
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