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   green and environmentally sustainable fabrication of cufe2o4/cuo-rgo@eosiny as photocatalyst for the synthesis of xanthene derivatives  
   
نویسنده samiee paghaleh effat ,kolvari eskandar
منبع شيمي كاربردي روز - 2023 - دوره : 18 - شماره : 69 - صفحه:85 -100
چکیده    One of the biggest challenges to the expansion of photochemical processes has been the creation of effective visible light photocatalysts for organic synthesis. heterogeneous photocatalysts present a favorable procedure to realize green and eco-friendly organic reactions. we fabricated the heterogenous catalyst cufe2o4/cuo-rgo@eosiny (ey) by immobilizing eosin on the substrate cufe2o4/cuo-rgo. the substrate of eosin was fabricated from the calcination of basil seed hydrogel (bsh) impregnated with copper and iron. the prepared heterogeneous catalyst as photocatalyst was applied in a green one-pot multi-component protocol for the production of biologically important xanthene derivatives via condensation of aromatic aldehydes and dimedone under the condition of visible light irradiation. the synthesized photocatalyst was characterized using various techniques such as ft-ir, xrd, and tga. the significant advantages of the present methodology include remarkable yield, cost-effectiveness, easy work-up, broad substrate scope, and significant reusability. the prepared catalyst was used four times without a significant decrease in reaction efficiency.
کلیدواژه basil seed ,eosiny ,reduced graphene oxide ,xanthene ,heterogeneous photocatalyst ,visible light
آدرس semnan university, department of chemistry, iran, semnan university, department of chemistry, iran
پست الکترونیکی kolvari@semnan.ac.ir
 
   green and environmentally sustainable fabrication of cufe2o4/cuo-rgo@eosiny as photocatalyst for the synthesis of xanthene derivatives  
   
Authors
Abstract    one of the biggest challenges to the expansion of photochemical processes has been the creation of effective visible light photocatalysts for organic synthesis. heterogeneous photocatalysts present a favorable procedure to realize green and eco-friendly organic reactions. we fabricated the heterogenous catalyst cufe2o4/cuo-rgo@eosiny (ey) by immobilizing eosin on the substrate cufe2o4/cuo-rgo. the substrate of eosin was fabricated from the calcination of basil seed hydrogel (bsh) impregnated with copper and iron. the prepared heterogeneous catalyst as photocatalyst was applied in a green one-pot multi-component protocol for the production of biologically important xanthene derivatives via condensation of aromatic aldehydes and dimedone under the condition of visible light irradiation. the synthesized photocatalyst was characterized using various techniques such as ft-ir, xrd, and tga. the significant advantages of the present methodology include remarkable yield, cost-effectiveness, easy work-up, broad substrate scope, and significant reusability. the prepared catalyst was used four times without a significant decrease in reaction efficiency.
Keywords basil seed ,eosiny ,reduced graphene oxide ,xanthene ,heterogeneous photocatalyst ,visible light
 
 

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