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synthesis and delayed germination of vinyl acetatebutyl acrylate copolymer for coating of sugar beet seeds using combined experimental design and image analysis
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نویسنده
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hamdi holasoo farahnaz ,nemati firouze ,amoozadeh ali ,sajjadi s. maryam ,taleghani dariush
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منبع
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شيمي كاربردي روز - 2019 - دوره : 13 - شماره : 49 - صفحه:21 -28
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چکیده
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Seeds are coated widely with different polymers for increasing productivity and improving stand establishment of different crops. emulsion copolymerization of vinyl acetate and butyl acrylate can be used for sugar beet seed coating. in this study, for the first time, a fractional factorial design, as an statistical experimental design method, was combined with image analysis method to achieve the optimal condition for emulsion copolymerization of vinyl acetate (vac) and butyl acrylate (bua) as a delayedgermination copolymer. the optimum condition was on the time of 3.16 hours, the temperature of 65˚c, the initiator concentration and anionic surfactant of 0.0121 wt%.the synthesized copolymer was homogeneous and was characterized using atrfourier transform infrared spectroscopy (atrftir), differential scanning calorimetry (dsc), particle size distribution (psd) and scanning electron microscope (sem) analysis. then the synthesized copolymer was used for coating of sugar beet seeds. the results show that the synthesized copolymer does not have adverse interaction with pesticides, fungicides and the color, which used for seed coating. therefore, it can be used in coating of sugar beet seeds. also, the synthesized copolymer delayed germination about 40 days.
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کلیدواژه
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vinyl acetate ,butyl acrylate ,delayed germination copolymer ,image analysis ,seed coating
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آدرس
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semnan university, department of chemistry, ایران, semnan university, department of chemistry, ایران, semnan university, department of chemistry, ایران, semnan university, department of chemistry, ایران, agricultural research education and extension organization(areeo), sugar beet seed institute (sbsi), lran
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Synthesis and delayed germination of vinyl acetatebutyl acrylate copolymer for coating of sugar beet seeds using combined experimental design and image analysis
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Authors
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Hamdi Holasoo Farahnaz ,Amoozadeh Ali ,Sajjadi S. Maryam ,Taleghani Dariush
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Abstract
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Seeds are coated widely with different polymers for increasing productivity and improving stand establishment of different crops. Emulsion copolymerization of vinyl acetate and butyl acrylate can be used for sugar beet seed coating. In this study, for the first time, a fractional factorial design, as an statistical experimental design method, was combined with image analysis method to achieve the optimal condition for emulsion copolymerization of vinyl acetate (VAc) and butyl acrylate (BuA) as a delayedgermination copolymer. The optimum condition was on the time of 3.16 hours, the temperature of 65˚C, the initiator concentration and anionic surfactant of 0.0121 wt%.The synthesized copolymer was homogeneous and was characterized using ATRFourier transform infrared spectroscopy (ATRFTIR), Differential Scanning Calorimetry (DSC), Particle Size Distribution (PSD) and Scanning Electron Microscope (SEM) analysis. Then the synthesized copolymer was used for coating of sugar beet seeds. The results show that the synthesized copolymer does not have adverse interaction with pesticides, fungicides and the color, which used for seed coating. Therefore, it can be used in coating of sugar beet seeds. Also, the synthesized copolymer delayed germination about 40 days.
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Keywords
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Vinyl acetate ,Butyl acrylate ,Delayed germination copolymer ,Image analysis ,Seed coating
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