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Microwave Assisted Eco-friendly Synthesis of Chalcones using 2,4-dihydroxy Acetophenone and Aldehydes as Corrosion Inhibitors for Mild Steel in 1M HCl
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نویسنده
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Verma Bhan Chandra ,Reddy Jayanth Mareddy ,Quraishi Ahmad Mumtaz
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منبع
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analytical and bioanalytical electrochemistry - 2014 - دوره : 6 - شماره : 3 - صفحه:321 -340
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چکیده
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In the present investigation we have synthesized four chalcones namely 3-(4-chlorophenyl)-1-(2, 4-dihydroxyphenyl) prop-2-en-1-one (chal-1), 1-(2, 4-dihydroxyphenyl)-3-p-tolylprop-2-en-1-one (chal-2) 1-(2, 4-dihydroxyphenyl)-3-(2-hydroxyphenyl) prop-2-en-1-one (chal-3) and 1-(2, 4-dihydroxyphenyl)-3-(4-hydroxy-3-methoxyphenyl) prop-2-en-1-one (chal-4) and premeditated their corrosion inhibitionproperty on mild steel (ms) in 1m hcl using chemical and electrochemical methods. thescanning electron microscopic (sem) study reveals the formation of protective film ofchalcones on ms surface. presence of elements on ms surface was also studied using highenergy dispersive (edx) technique. potentiodynamic polarization study reveals thatchalcones are of mixed type inhibitors. weight –loss experiment also performed at differenttemperature in order to derive thermodynamic parameters and to explain mechanism ofadsorption
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کلیدواژه
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Mild steel ,EIS ,Corrosion ,SEM-EDX
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آدرس
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Banaras Hindu University, Department of Chemistry, Indian Institute of Technology, Banaras Hindu University, Varanasi 221005, India, India, Banaras Hindu University, Department of Metallurgical Engineering, Indian Institute of Technology, Banaras Hindu University, Varanasi 221005 India, India, Banaras Hindu University, Department of Chemistry, Indian Institute of Technology, Banaras Hindu University, Varanasi 221005, India, India
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پست الکترونیکی
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maquraishi.apc@itbhu.ac.in, and maquraishi@rediffm
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Authors
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